Friday, November 29, 2019
Gps Essays - Global Positioning System, Navigation, Geolocation
Gps Describe how GPS works and how normal citizens have been able to use it to make their lives easier. GPS is a global positioning satellite that is used to show the exact position on earth that you are. This system is used in many ways. Many people in a new city use rental cars. These people will probably get lost. Now in these cars there is GPS. This system allows the driver to know where they are and gives them a map of the place they are planning to visit. GPS also speaks to that person and lets them know whether they missed the street they had to turn on, or how far to their destination. This new system can also help fisherman. Sometimes, people who fish for a living have a heard time finding good schools of fish. The GPS system is a great assistant in these situations. By using the tracking system it helps find where most of the fish are living. Now if a fisherman has a good day and wants to return to that spot another time, the GPS will save the location in its memory. Thus, allowing the fisherman to return to that exact position anytime he pleases. Another way this system helps normal citizens is by making research a lot easier. For the scientists who study many living things, GPS makes their job a little easier. Many researchers who study whales use GPS as a tracking device. When the whale comes up to breathe the scientist shoot a radio tag on to the whale. This enable s them to track the whales life and record information. Elephants are other animals that are tracked by GPS. A collar is put on wild elephants. This collar tracks the elephant wherever it may go. From then on, scientists record information on the elephants. We can also see life from an elephant's point of view. The collar also records growth and biological statistics and when we need them, we track the elephant and download the research on to a computer. Acceptance Essays
Monday, November 25, 2019
Advantages and Disadvantages of Being Famous â⬠Creative Writing Essay
Advantages and Disadvantages of Being Famous ââ¬â Creative Writing Essay Free Online Research Papers Advantages and Disadvantages of Being Famous Creative Writing Essay Now itââ¬â¢s my task to write an essay on advantages and disadvantages of beeing famous. I think everybody in the world want to earn a shit load of money like all the famous stars. But, I think earning a lot of money is not all, you must also have friends, a family staying behind you, a girlfriend or a boyfriend, because without all these things you are lonely. But, an other point is, that you can buy a big house with you money, a lot of cars, house maids and drivers. But, when you are famous, many paparazzi follow you every day, every time. And so you are under control every time, and if you do something wrong, everybody get to know it. An other disadvantage is much stress. You travel all day around the world, go to awards and so on. And if you have stress, you may take drugs and alcohol. Without taking drugs many stars wouldnââ¬â¢t have bear the stress. Let me go over to the end of the cariers of stars. If the carier of famous stars end they run short of money. If they didnââ¬â¢t save enough money for the ending of their lifes, they will get a problem. Only some stars manage to earning enough money, for example Robbie Williams or Madonna. An other problem is kidnapping children of the stars, because of the lot of money th stars have potential kidnapper hope for lots of money by kidnapping starââ¬â¢s children. All in all I can say on the one hand I want to become famous, because of the money, but on the other hand I donââ¬â¢t want to become famous because of much stress, the paparazzi and the dangerous life. But, maybe I habe the chance to become famous and then I will realize it. Research Papers on Advantages and Disadvantages of Being Famous - Creative Writing EssayThe Effects of Illegal ImmigrationIncorporating Risk and Uncertainty Factor in CapitalWhere Wild and West MeetThe Relationship Between Delinquency and Drug Use19 Century Society: A Deeply Divided EraResearch Process Part OneComparison: Letter from Birmingham and CritoHip-Hop is ArtQuebec and CanadaTwilight of the UAW
Friday, November 22, 2019
Change Management Assignment Example | Topics and Well Written Essays - 2000 words
Change Management - Assignment Example The postal organization specializes in courier and express services (Australian Government, 2011). The organization is trying to expand business in the field of retail merchandise and agency services. Traditional postal service business had become unprofitable in last few years. The concept of traditional postal communication has changed due to evolution of email communication, social networking. People prefer to use internet communication rather than traditional postal services. The postal organization has incurred a loss of $90 million in last 5 years. Australian Post is trying to change business strategy in terms of shifting focus on retail Merchandise and agency Services. They need to manage the change process carefully. Change management will help them to build a strong organizational framework. Change Management Change management tries to integrate different systems and structure with the organizational structure of the company. Change management can be applied in the transitio n phase of the organization. A company can go for whole system change or partial system change. Many organizations use ADKAR change management model to improve productivity. Dupont is a well known chemical company of USA. They used the model to implement change management in the production process. ADKAR model can be explained in the following way. A- Awareness is generated for change. Top management of the company identifies problem areas like staff productivity, poor service delivery, poor annual sales volume and low productivity of existing system. The management then decides to change existing process. D- Existing employees express desire to participate in change process. They can be termed as change agents. K- Knowledge in terms of training and development is given to the change agents. The knowledge process helps them to understand key issues of new system. A- This is the application part of change management. In this phase organization starts to use new implemented system. Or ganization takes external help to implement new system. The external system monitors the application phase. Coaching and mentoring are required to manage change agents. R- Organization tries to reinforce the sustainability factor. Companies try to maintain the new implemented system. They try to analyze the result of change management in this phase. Change management is a dynamic process. Organization can implement change management program in various areas like marketing, production process, financial management system and organizational structure. Change management can be implemented by altering the thinking process of existing employees. It is very difficult to find employees who accept change very successfully. The organization needs to select change agents ready to accept new system. Service based models like changing customer relationship management requires rigorous training and development program. Top level management needs to communicate with change agents regularly. Study shows that at least 15 engagements are required to clarify the objectives of top management (University of Pennsylvania, 2010). Change Management in Australia Post Australia Post has business expertise in the field of postal services (like letter and parcel delivery, courier services). The organization is trying to expand business in the field of third party agency services like banking, bill payment, insurance, passport application and
Wednesday, November 20, 2019
Wannaburger Restaurant Assignment Example | Topics and Well Written Essays - 1500 words
Wannaburger Restaurant - Assignment Example This ensures the business can make the appropriate changes in ensuring they reach at the forecasted results. However, neglecting the measurement of all the objectives will not likely give the required performance. For example, when a business wants to improve in its sales, it should give a measurement on the planned improvement (International Institute of Business Analysis, 2005). Leaving out this particular aspect does not give an approach that will be instrumental in the improvement. Therefore, there is a need to look at measurable objectives before stating an approach in solving the incumbent issues. In this case, Wannaburger restaurant wants to make an improvement in its performance since the situation is not appealing. Therefore, it has to make succinct approaches in ensuring it has achieved what it wants both in the long term and in the short term. This is an approach that will guarantee better performance in terms of offering its services and products to the market in need. Th erefore, the business has to put its focus on the best approach that will increase its performance (Palepu and Healy, 2007). For example, the business has to make use of a better marketing mix that will attract a larger part of the market in demand for its products and services. Attracting a larger part of the market guarantees that the business will have an increase in the turnover. This means that their products will be highly demanded by the market (Hay, 2003). This will directly reflect an influx in the revenue of the business as it will garner more sales. This will in the end give a positive result on the profitability of the business. First of all, the business has to look for ways of enhancing its product. Most of the people in the market only appreciate the product and services that are offered. The market does not look for other aspects that are involved in the business and this could affect the business. For example, when a market is attracted to the quality of a product o r a service, they will continue using the product or service due to its quality. When the quality of the product or good is enhanced, the product or service will attract an even larger market. Therefore, enhancing their product is one of the aspects that should be considered. For example, when the quality of a product deteriorates, the market is likely to look for alternative products that have more quality (International Institute of Business Analysis, 2005). As such, the business is likely to loose a number of its esteemed customers due to deteriorating quality of products. Therefore, if the business wants to give a positive performance in the market, it should look forward into improving its products and services that are offered to the market. This will attract an even larger market in need of its products and services. In addition to this, the business should look at its competitors. When competitors are making an improvement in their businesses, other businesses have to take t he same route. This is due to the attraction the business poses to the market. With improved service and product delivery, the business is likely to attract a larger part of the market. The second aspect that should be considered in plotting a solution inn this scenario is the bordering market. At times, market expansion improves the performance of the business. For example, the business is likely to record an increase in the number of people that are allied to the services and products that are sold by the business (International Institute of Business Analysis, 2005). Therefore, this is a considerable approach that should be taken by Wannaburger restaurant. Apparently, an approach that would be used in this aspect is enhancing the market that borders the
Monday, November 18, 2019
Microsoft Essay Example | Topics and Well Written Essays - 500 words - 2
Microsoft - Essay Example r of business organizations compete with Microsoft using an open source commercial model by adjusting and then dispensing open source software to customers at insignificant costs and thus earn revenue on complimentary products and services. Such businesses do not bear the total costs of development and research for the software. Further, advertising-based firms models look for revenue through delivering third party adverts to final consumers who get the software at no direct cost as Microsoft pays for the costs indirectly. Benefits in market acceptance of advertising or open source based software may unfavorably affect the companyââ¬â¢s revenue, sales, and operating margins. The total subscription and license costs can vary depending on the available license levels and having a Software Assurance license. Microsoft Company has adapted the Elixir Workflow system, which is rich, web-based settings that that lets Microsoft connect many processes and people into certain business projects or activities. By using this technology, predefined business rules are achieved to get the company on toes. It manages and tracks different tasks linked to a project from distinct actions to approvals. This technology has helped Microsoft to visualize its daily operations and identify areas of productivity advancements. The Elixir Workflow System is configured based on the rights of the users and preferences. This ensures efficiency in production processes and security for the products (Lopatka and Page, 2007) With the use of Elixir, multiple applications can be achieved with only one interface. This provides Microsoft with a flawless approach to interoperability. For precise productivity, the system offers a full set of trading process management operations including decisions and branching, event-driven interactions, and automated activities. Generally, the Elixir Workflow System is a significant technology to Microsoftââ¬â¢s productivity as it integrates various Computer programs
Saturday, November 16, 2019
Structure of Water and Its Dynamic Hydrogen Bond Network
Structure of Water and Its Dynamic Hydrogen Bond Network Introduction Water is essential to life as it is main constituent of cell in living organism. All biological macromolecules are almost inactive in its structural stability and functioning in absence of water. Water-Role in Life Water is key compound for our existence on this planet due to its ubiquitous presence on the earth and in living organisms. It is involved in all chemical, biological and geological processes. Due to its anomalous behavior it named as ââ¬Ëmatrix of lifeââ¬â¢, ââ¬Ësolvent of lifeââ¬â¢. It plays a vital role from molecule and cell to tissues and organisms.1-4 In past several decades water has attracted the most scientific attention among the liquid due to its anomalous properties. It shows peculiar properties such as negative volume of melting, density maximum at 277 K, high melting and boiling point, high dielectric constant, minimum in the isobaric heat capacity and isothermal compressibility at 308 K and 319 K, respectively, high mobility transport for H+ and OH ions. The density of most liquids increases as it freeze but in case of water it expands about 11% due to which ice floats on water. It is the solvent of life and plays an important role in protein interactions a nd stabilization of protein structure. The work of Kauzmann gives the importance of water in protein folding and its interactions with water.5 Structure of Liquid Water The anomalous behavior of water is due to its unique ability to form a network of self associated molecules through hydrogen bonding. To study the structure of water and its dynamic hydrogen bond network large number of studies has been carried out.1-12 Still many aspects of water are not fully understand at molecular level. Dyke and co-workers first reported existence of H-bonding in vapor phase experimentally and measured the H-bond length as 2.98 Ã⦠in water dimer using molecular beam resonance technique which is higher than water in solid (for ice H-bond strength 2.74 Ãâ¦) and liquid (2.85 Ãâ¦) indicates the H-bond strength is weaker in Gas phase.13 From X-ray diffraction study of Bernal and Fowler and Morgan and Warren it is revealed that water is tetrahedrally coordinated through hydrogen bonds similar to the structure of ice I (Figure 1.1). 14-15The number of theories for the water structure has been proposed based on different techniques such as X-ray, neutron diffraction, dielectric relaxation and Raman spectroscopy. 16-22. These theories are generally classified into two models as a) Continuum model and b) Mixture model. Figure 1.1 Crystal structure of ice I at low pressure Continuum model In continuum model it is assumed that almost completely hydrogen bonded water molecules in a continuous network. Pople described the continuum model which is agreement with the observed variation of X-ray radial distribution function with temperature. 23According to Pople In continuous bonded network of the water bond bending and deformations occurs instead of bond water. Recently, Rice and Sceats 24proposed Random Network Model (RNM), which explains the continuum model and it is further developed by Henn and Kauzmann. 25This model is used for determining the heat capacity contribution due to water-water interactions. b) Mixture model In mixture model water consists of differently H-bonded species with zero, one or both hydrogens are engaged in hydrogen bonding. Franks and Wen 26 gives the ââ¬Å"Flickering Clusterâ⬠model in which cooperative H-bonding is observed in water molecules. The co-operativity involves the hydrogen bond formation of one bonding site of water molecule contributes the delocalization energy to the molecule, which is involved in hydrogen bonding with another water molecule. According to Franks and Wen the clusters of the water molecules (bulk water) and free monomer molecules (dense water) are in equilibrium with each other. Samoilov 27 proposed the interstitial model in which water molecules are present in the cavities of ice lattice. Nemethy and Scheraga 28 used statistical thermodynamic model to calculate the Helmholtz free energy, internal energy and entropy as a function of temperature. Also the water hydrate model proposed by Pauling. 29 Now a days, theoretical techniques such as Monto Carlo, molecular dynamic simulation are used to study structural behavior of water. It provides most promising approach for the study of water at molecular level. Jorgensen 30 has developed transferable intermolecular potential functions (TIPS) suitable for use in liquid simulations for water. This potential has been used by Jorgensen and Madura 31 in MC simulation on liquid water to study the effect of temperature on vaporization, hydrogen bonding, density, isothermal compressibility and radial distribution functions. Number of water models such as SPC, TIP3P, TIP4P, TIP5P are developed for the molecular simulation of large biomolecular systems. Figure 1.2 Frank-Wen Flickering Cluster Model of Liquid Water 1.2 Hydrophobic Hydration and Hydrophobic Interactions The weak non-covalent interactions like van der Waals forces, H-bonding, ion-dipole, hydrophobic interactions are responsible for change in the structure of water around the solute molecule. The hydrophobic interaction is the prominent factor in the solvation of apolar or non-polar molecule. When a non-polar solute is dissolve in water there is large negative change in entropy. The disruption in the normal H-bonded structure is occurred and new H-bonded cage-like structure is formed around the solute molecule. So the structure formed is more ordered than the ordinary water. The term hydrophobic hydration is used when non-polar solute solvated by the cage of the solvent molecule around it. The short lived aggregates are formed around the solute molecule. The formation of polymeric aggregates strengthens the hydrogen bonding which gives negative contribution to ÃâH0. 10 The hydrophobic interactions are important in a field of biochemistry for the purpose of conformational stability of biological macromolecules, protein folding, aggregation, ion transport, drug delivery as well as in industry. Usually hydrophobic hydration occurs in non-polar compounds such as alcohols, ethers, and amines. The tetraalkylammonium (TAA) salts with larger cation also shows the hydrophobic hydration effect. Kustov gives the effect of size of cation on the hydrophobic hydration. He studied the specific heat of solution for the higher size cation TAA salts and observed that as the size of cation in salt increases the specific heat of solution and hydration increases upto the tetrapentylammonium salts and then decreases. As the specific heat of solution increases the hydrophobic hydration increases. For the hexyl and heptyltetraalkylammonium salts the ÃâC0p decreases so the hydrophobic hydration weakens. Thus hydrophobic hydration depends on the size of cation of TAA. Th e hydrophobic interaction is best explained by Goring et al. by studying the interaction of non-electrolytes in aqueous solutions by dilatometrically. They compared the apparent specific volume (à â⬠¢2) relative to apparent specific volume at 0 à ºC as function of temperature for non-electrolytes and showed that 1-butanol behaves like hydrophobic compound and acts as structure maker in aqueous solution while glycerol with polar groups disrupts the structure of water. The hydrophobic compound shows the slope dà â⬠¢2/dT is less than the corresponding thermal expansions of pure compound while it greater for the hydrophilic compounds. Madan and Sharp explained that non-polar solutes have large capacity heat of hydration ÃâCp while for polar solutes it is small negative. The large change in heat capacity at high temperature is due to unfavorable enthalpic interacions and not due to entropy change. The effect of salt on the hydrophobic hydration was carried out by Talukdar and Kundu and observed that hydrophobic cation induce more hydrophobic hydration in aqueous NaNO3 solution than in pure water. Rossky et al. with the help of computer simulation studied the hydration properties of the interfaces between the water and the hydrophobic surfaces for the active peptide melittin in its monomeric and dimeric form and concluded that hydrophobic hydration is depends on the surface topography of biomolecule. 1.3 Spectroscopic study of water Due to its various anomalous properties and great importance in the several field water is the most studied compound. To study the structure of water, number of spectroscopic techniques such as IR, Raman, neutron diffraction, X-ray scattering, NMR spectroscopy etc. have been used still today. The spectroscopy and scattering studies provides the structural information of water at molecular level. Bernal and Fowler analyzed the X-ray diffraction of water and investigated water as distorted quartz-like. The hydrogen bond network in water is found to be tetrahedral in nature and each water molecule can be bound with another four water molecules i.e. each water molecule is double proton donor and double proton acceptor. While recently, Wernet et al. studied the structure of water by soft X-ray absorption spectroscopy and X-ray Raman scattering and investigate that hydrogen bond network in the water consists of only two strong hydrogen bonds and one act as proton door and another as proton acceptor. This controversial result of structure of water from earlier study makes the scientist to study the water structure more interesting. In this context, number of scientists have been studied the water structure by X-ray absorption spectroscopy. Infrared and Raman techniques are also the important sources of the information of hydrogen bonding in water. Above the absolute temperature all the atoms in the molecules are in continuously vibrating motion with respect to each other. Any molecule absorbs the radiation when frequency of a specific vibration is equal to frequency of the IR radiation directed on the molecule. Each atom has three degrees of freedom, corresponding to motions of the three Cartesian coordinate axes (x, y, z). Total no of coordinate values is 3N for a molecule containing N atoms. Thus, Water has 9 degrees of freedom with C2v symmetry. It shows the two stretching vibrations (symmetric and asymmetric), one bending vibration, three hindered rotations (librations), and three hindered translations. Earlier, number of research papers has been published on the study of the structure of water in solid, liquid as well as in vapor phase by IR and Raman technique. The fundamental IR frequencies for the H2O and heavy water is as shown in Table Table: Fundamental vibrations of liquid ordinary water and heavy water Vibration(s) liquid H2O (25 à °C) liquid D2O (25 à °C) liquid T2O v, cm-1 à µÃ », M-1cm-1 v, cm-1 à µÃ », M-1cm-1 v, cm-1 v2 1643.5 21.65 1209.4 17.10 1024 combination ofv2+ libration 2127.5 3.46 1555.0 1.88 v1,v3, and overtone ofv2 3404.0 100.61 2504.0 69.68 2200 http://www1.lsbu.ac.uk/water/water_vibrational_spectrum.html Walrafen investigated the structure of water by Raman spectroscopy in the intermolecular as well as intramolecular vibrational region. From Raman scattering it is observed that for liquid H2O and D2O a broad weak hydrogen bending band at 60 cm-1 and it is observed to be decreases as temperature rise, the band near 170 cm-1 is produced by the stretching motion of O-H band in water molecule. This is also decreases as increases in temperature which indicates the structural breakdown of water units. These vibrations are the intermolecular vibrations of water which are observed in the restricted translational region. The intramolecular vibrations of water occurs in the range of 2000-4000 cm-1.Walrafen studied the Raman spectra of 50 mole % solution of H2O and D2O in the intramolecular region in which principle contribution of HDO vibrations are studied. The two maxima at 3415à ±5 cm-1 and 2495à ±5 cm-1 are referred due to OH and OD stretching vibrations of HDO, and of H2O and D2O. Also the weak band at 2860à ± 10 cm-1 arises from the overtone of the fundamental intramolecular bending vibration of HDO near 1450 cm-1. When H2O, D2O mixture studied at 32.2 to 93 à ºC, the isosbestic point observed at 2570à ±5 cm-1 indicates the equilibrium exists between hydrogen bonded and nonhydrogen bonded OD stretching vibrations. Senior and Verrall observed same results when studied the HDO stretching at temperature 29 to 87 à ºC by infrared spectroscopy. Bakker et al. studied the lifetime of the OH-stretching vibration in the water as a function of temperature by using femtosecond mid-infrared pump-probe spectroscopy and observed that it increases from 260à ±18 (at 298 K) to 320à ±18 (at 358 K) Recently, molecular dynamic simulation is becomes the fast method for the structural detection at molecular level. Xantheas et al. used the ab initio method to obtain the vibrational frequencies as well as zero point energy for the water clusters and its isomers with the help of second-order Mà ¸llerââ¬âPlesset perturbation level of theory (MP2) with the augmented correlation consistent basis set of double zeta quality (aug-cc-pVDZ). 1.3.1 Near-Infrared spectral study of water and aqueous solutions Near-Infrared consists of the region 800-2500 nm (12500-4000 cmââ¬â1) in the electromagnetic spectrum. In this region molecule have energy sufficient to excite first (2à ½), second (3à ½), and higher overtones (nà ½) vibrations. The overtones observed in the molecule when the intermolecular vibrations of the molecules do not obey the Hookââ¬â¢s law. The band is more intense when the greater the anharmonicity. The combination bands are also observed in the same region. Near infrared spectroscopy is the basic tool to study the hydrogen bonding in molecule. Earlier, the scientist Luck studied water and alcohol in the NIR region and observed that the strength of cooperativity of H-bond in water is about 250 % stronger than H-bond in a monomeric water. Different species of water present in the cooperative H-bond such as H-non bonded, H-bond strong and H-bond weaker. Ozaki et al. studied the structure of water by using two analytical techniques such as two dimensional correlation spectroscopy and principal component analysis in which they showed the two-state water model by measurements of the water at different temperatures from 6 to 80 à ºC. Two bands are observed at 1412 and 1491 nm due to two different species of water i.e. weak H-bond and strong H-bond respectively. The species observed at 1438 nm which has no much effect of temperature which suggested may be due to distorted two-state model of water. The water at high temperature and pressure rem arkably exhibits different properties than at ambient temperature. It becomes good solvent for hydrophobic substance such as benzene and hydrocarbons which are non-polar gets completely miscible at certain temperature and pressure. The effect of high temperature as well as pressure has been given by Ikawa et al. in the range of 5500 to 7800 cm-1. They observed the band at 7000 cm-1 gradually shifts to higher wavenumber is due to free OH vibrations and at 673 K and 400 bar pressure the absorption band retain the rotational features i.e. water molecule quite rotate freely though there is collision with other molecules. Recently, Near-Infrared spectroscopy has been used extensively for chemical analysis and characterization. The applications of NIR spectroscopy in various fields have attracted the scientific community. It is also used in the determination of moisture content in food samples. It can be used to probe the hydration effects in aqueous solutions of salt. Wu et al. have studied the effect of ethanol on the structural organization of aqueous solutions of [Bmim][BF4] and [Amim][Cl] using one-dimensional and 2D correlation NIR spectroscopy. They showed that hydrogen bonding between water and ILs gets reduced in presence of high concentration of ethanol32 and can be used to remove water as an impurity in hygroscopic ILs. They also used this technique to study aggregation behavior of ILs in water. NIR spectroscopy has been used previously for the study of hydration by McCabe and Fisher in which they have studied the hydration of perchlorate and alkali halides in aqueous solutions by using excl uded volume. Koga et al. have given the excess molar absorptivity in the range of 4600-5500 cm-1 i.e. (à ½2+à ½3) combination band of water for the Na halides and concluded that the Brââ¬â and I form the hydrogen bond directly with the water network which is different than the Cl ion. Bonner and Woolsey have obtained the hydration number for some alkali halides by using the 958 nm (2à ½1+à ½3) combination band of water. By applying their method, Hollenberg et al. calculated the hydration number for amino acids and carbohydrates The new concept introduced by Noda in 1993 i.e. two dimensional correlation spectroscopy has attracted many scientist to study effect of solutes on the structure of water by IR as well as NIR spectroscopy. This technique becomes powerful tool for the elucidation of spectral changes induced by temperature, time and concentration. Noda et al. studied the structural and crystallization dynamics of poly(L-lactide) during isothermal cold crystallization by two dimensional correlation spectroscopy. An interpretation of the evolution with temperature of the à ½2+à ½3 combination band in water V. Fornà ©s and J. Chaussidon, J. Chem. Phys. 68, 4667-4671 (1978) Near-infrared spectroscopic study of water at high temperatures and pressures Yusuke Jin and Shun-ichi Ikawa J. Chem. Phys., 119(23), 12432-12438, 2003. The importance of cooperativity for the properties of liquid water W.A.P. Luck Journal of Molecular Structure, 448 (1998) 131 142. Studies on the Structure of Water Using Two-Dimensional Near-Infrared Correlation Spectroscopy and Principal Component Analysis V. H. Segtnan, S. Sasic, T. Isaksson, Y. Ozaki Anal. Chem. 2001, 73, 3153-3161
Wednesday, November 13, 2019
Student :: essays research papers
Throughout the eighteenth century until the nineteen fifties, different countries have participated in the acts of industrialization and modernization more fully then others. There were many factors that permitted these countries to industrialize and modernize at a much greater pace than their significant opponents in the world industry. While rapid urbanization in Britain and dictatorship in Argentina and Russia promoted industrialization and modernization, the imperialist policies and ideas of Britain hindered industrial development in Egypt. Rapid urbanization played a very important role in the industrialization and modernization of Britain. Industrialization was a long hard process in Britain; however they were the first group of people to undergo this long process. The reason industrialization occurred in Britain was due simply to the fact that they had an astronomical jump in population. Within a one hundred year span, Britainââ¬â¢s population grew from 5.5 million in 1750 to over 16 million in 1851. The large population growth caused a great deal of economic and agricultural improvements for the British people. Farming was made easier and more efficient due to England undergoing a process of agricultural improvement that enabled fewer farmers to feed more people while cultivating the same amount of land. ââ¬Å"People also migrated at an unprecedented rate- from the Countryside to the citiesâ⬠(Bulliet, page 610). This caused a great population shift from the agricultural southeast to the midlands and t he north. Due to the fact that people started to search for jobs, a large portion of the population started to migrate to the midlands and the northern parts of the country; this gave a large source of inexpensive labor for the rich business owners to profit. (Bulliet, pages 609-612) A great deal of the British Industrialization was involved in the cloth and clothing industry. Britain was importing raw material such as cotton and silk from India, mass producing it, and then selling it back to India for an enormous profit. Now that urbanization brought a huge amount of the labor force to the factory towns and cities, this made it so that Britain could now produce more and more cloth and before they even knew it they were the largest producers of cloth in the world. (Bulliet pg.610) Historians propose a number of reasons for the cause of industrialization and modernization in Britain. Among the most persuasive is the enormous increase in food production following the establishment of the enclosure laws of the
Monday, November 11, 2019
Enabling Learning and Assessment Essay
1. The purposes of assessment Assessment is the process of evaluating an individualââ¬â¢s learning. It involves generating and collecting evidence of a learnerââ¬â¢s attainment of knowledge and skills and judging that evidence against defined standards. Tummons suggested that: ââ¬ËWith assessment we can: * Find out if learning has taken place; * Diagnose learners needs; * Provide public acknowledgment and certification of learning * Allow processes of selection to be carried out; * Provide way to evaluate learning programmes; * Motivate and encourage learners.ââ¬â¢ Tummons (2009:5) Written justification of assessment methods I have chosen to do Holding and aiming in the prone position, I would do this by getting the SUT in the tramline formation. This is where they will number off in pairs, so all the No.1ââ¬â¢s on one side of the room whilst all the No.2ââ¬â¢s are on the other side of the room. I will get the No.1ââ¬â¢s to conduct the drill when I give the word of command. The No.1ââ¬â¢s will be ensuring they adopt the prone position correctly, going through the 9 key point check list and taking aim on the target. Whilst this is happening the No.2ââ¬â¢s will be observing throughout looking for any mistakes. Once the No.1ââ¬â¢s have completed the drill I will go down the line asking the No.2ââ¬â¢s if they observed any mistakes. By doing this I am getting the SUT to give out peer assessment on the progress of his/hers drill on the weapon system as this can develop and motivate student. The student will also have their own self assessment; this is where the students are assessing their own progressà throughout the lesson. These methods encourage the SUT to make decisions about what has been learnt so far, and to reflect on aspects for further development. Once the No.1ââ¬â¢s have completed the drill, the same process will happen with the No.2ââ¬â¢s and the No.1ââ¬â¢s looking and observing for any mistakes. Whilst all this is going on I will be looking for any mistakes as I watch from one end of the tramline formation, this is called tutor assessment and can help give feedback to the student to guide them on their strength and areas of development. This is also known as formative assessment so it can provide for me a continuous source of information about the studentsââ¬â¢ progress, improvement and problems encountered in the learning process, so I together we can develop their confidence and competence on the weapon system. 2. Practical assessment a) Aim The aim of a practical assessment in a classroom environment is to ensure that when handling a weapon system that the necessary measures and safety precaution is carried out correctly and sufficiently. It is my aim to make sure that the SUT carry out the drills correctly, if however people are struggling to adapt to the new drills then itââ¬â¢s up to me the instructor to change my approach to the individual learning style. b) Reason for selecting practical learning assessment We use practical assessment in the army especially when teaching a particular subject like Skill at Arms to help us as a teacher to confirm that the SUT have understood the correct handling of the weapon. Itââ¬â¢s not only a confirmation for the teacher but a confirmation for the individual that he/she has took on board the new skill and knowledge they have been taught in the lesson. During the lesson, when I have demonstrated a new drill, the SUT are required to imitate the drill whilst I explain and demonstrate it, taking it step by step. Once I am happy that the SUT have grasped the new drill, a confirmation is done to ensure that the SUT understands the newà weapon drill. This will be done when I give the word of command and the SUT carrying out the drill without any help or guidance as I watch and observes for any mistakes that the SUT may do. In order for the SUT to use blank or live ammunition on exercise or on the ranges, they are required to pass a Weapon Handling Test (WHT) which is a critical practical assessment as it is part of their summative test and needs to be done twice a year. I will give a number of instructions which the SUT must complete correctly and confidently in order to pass. There is no time limit and they are allowed one mistake on each stage of the test. This assessment is to show that he/she has the knowledge and skill to handle the weapon with blank or live ammunition with confidence. For assessment of practical activities, the potential barriers should be considered and reasonable adjustments developed that meet the needs of the individual learner. Many of the adjustments for a practical assessment are similar to those of a written assessment. We must however be aware of the learners/individual learning styles as this will vary across each lesson we teach. If we look at Fleming understanding of learning styles which he used the terminology of VARK, he stated that people can be grouped into four styles of learning: * Visual ââ¬â Seeing. * Aural ââ¬â Listening and talking. * Read/Write ââ¬â Reading and writing. * Kinaesthetic ââ¬â Doing. (Gravells 2012:40) The SUT will come under one or more of these learning styles and as I have seen it in the past whilst teaching, I have to adapt as a teacher to accommodate to their preferred learning style which means I have to plan and break down my lesson to ensure all SUT get the full benefit of what is being taught to them. Sue Crowley of the IFL stated: Often new teachers teach as they were taught, then perhaps as they would likeà to have been taught, and finally they realise different ways and a wider spectrum of teaching and learning approaches are needed and available. (Gravells 2012:40) A statement in which I agree upon as my thought process was similar but when teaching SUT itââ¬â¢s taught me to adapt my teaching skills to benefit the individuals so they can get the best outcome during the lesson. c) Conduct of the practical assessment The SUT will be assessed throughout the lesson and this can be done in many ways as it is classroom based, this will be an informal assessment. As the SUT reacts to the word of command for example; ââ¬ËFor inspection port armsââ¬â¢ they are to carry out the necessary drill in which I will observe for mistakes. Observation is a good way to assess the skills, knowledge and attitudes of the SUT. When observing, it enables me to see how well the SUT are doing, letting them make mistakes as long as it is safe, especially when dealing with a weapon so they can learn from their own mistakes. Once the drill is complete I can ask each individual if they made any mistakes and give them self assessment, otherwise I can give negative or positive feedback to the SUT. Observation is good within our training establishment as it assess the SUT competence, skills and attitudes when dealing with a weapon and the observation can follow on with a question to check the knowledge and understanding. SUT training can be assessed in two other ways and they are called peer assessment and self assessment. For the instructor to see this happen, the students will pair up and work as a team. Whilst one SUT does the drill on the weapon whilst the other partner watches for mistakes, this is called peer assessment, but at the same time SUT who is carrying out the drill can self assess as he/she goes along. If the student was to carry out the Load, Ready, Unload drill, their partner can look in for any mistakes and as the instructor asks the observer from each team if there were any mistakes, this can be useful to develop and motivate the SUT. Peer assessments can be affective as SUT feedback is given skilfully, but other students may think more about what their peers have said than about what the instructor have said. 3. Question assessment a) Aim The aim of a question assessment is for the instructor to see if the SUT can demonstrate knowledge and understanding of the subject being taught to them. It also helps when asking a question to the SUT that they have to think about their answer. b) Conduct of a Question assessment During each lesson throughout the army, as an instructor we will always ask the SUT questions of the particular topic that we have been learning about before moving on to the next topic or next stage of the lesson. This is formal or informal assessment and is used to assess cognitive ability which can be used whenever the instructor wants to assess the knowledge and understanding of SUT. When giving a lesson on Skill at Arms, ââ¬ËDifferent combat position.ââ¬â¢ The instructor will always give an explanation of why we do it and when to incorporate the positions for example, on the ranges or when we are on operational tour, followed by a demonstration. As the instructor has given the explanation and demonstration, we will go through the demonstration again whilst the SUT imitate you as you take them through step by step. Whilst doing this process we normally ask the SUT questions on the next stage of the movement, pausing for a second and then state the name of the learner who can answer. This way, all SUT is thinking about the answer as soon as you have posed the question, and is ready to speak if their name is asked. This assessment not only help the instructor to confirm that the individual or group know the answer but helps their peers to understand it as well. We also do oral written assessment, as this is partà of the minimum core, for example before I start the lesson I would ask the SUT to take out their note books and pens. I will ask them a number of questions in which they will write their answers in their note books which will be marked before the lesson take place. If for some reason some of the SUT get a few questions wrong I will ensure that I make a plan in the evening to go through the questions or drill in which they got incorrect so that they are at the same stage as all the other SUT. Asking questions to the SUT and for them responding in giving the answers back to the instructor is self assessment and peers assessment so that the SUT know what areas they are good at and what areas they need to work on. However itââ¬â¢s good for the tutor assessment to understand how the SUT progress is going by conducting these assessments. C)à Advantages| Disadvantages| Problems can be solved| SUT donââ¬â¢t know the answer| Question being answered| SUT can be put on the spot| Understanding peopleââ¬â¢s views and opinions| | Gives people a voice| | 4. Reflecting on how feedback has informed your learnersââ¬â¢ progress and achievement Feedback is a vital part of the learnersââ¬â¢ training at the army foundation college as it informs the SUT on their progress and achievement. To make sure it is effective it is important that we develop rapport, mutual respect and trust between the instructor and the SUT. During a Skill at Arms lesson it is important to give effective feedback as this informs the SUT on how well they are doing or on what areas they might need to work on. I try to give out the best feedback as I can to the SUT or the individual as I know this will help reassure, boost confidence, encourage, motivate and develop their knowledge, skills. It can help the SUT to maximize their potential and professional development at different stages of training, raise their awareness of strengths and areas for improvement, and identify actions to beà taken to improve their performance. 5. Reflecting on how feedback from others has informed your own professional practice On the 1st November 2012, I conducted a lesson on pain relief (Morphine) which was observed by an assessor. I felt that the lesson was well structured, planned and I got the key learning points across to the SUT. Once the lesson ended I sat down with my assessor and was given feedback on my lesson. The written feedback said this: The session had a clear and important content to communicate. This was achieved and checked by the test. A stronger introduction would set the scene and provide guidance to learners of what they had to do during the lesson. Focus on the test/know the purpose of the test. The conclusion could tell learners what to do with the test papers and how this will be an aide memoire. Test was very well created, covering all key learning and checking recall, understanding and application. It could be improved with clear guidance i.e. working individually without referring to their notes. As this was ââ¬Ëassessment for learningââ¬â¢ as well as ââ¬Ëassessment of learningââ¬â¢ learners could work individually, with a partner and finally as a whole group to get the answers/self assessment and check learning. You could get feedback on results from the test by asking those who got 100% to stand up ââ¬â an energiser, positive motivation and a simple measure for you. This feedback has opened my eyes a lot clearer as I was more channelled to delivering a simple but constructed lesson. Just by delivering a stronger introduction can make the learner motivated to learn, which I didnââ¬â¢t realise until someone made it aware to me. It was a good motivation and energiser to hear from the assessor that the test paper was well created which gave me that sense of pride. However when it came to handing out the test paper, giving the SUT a certain amount of time to do it in and once they had completed it they would mark their own paper as I went along with the answers. Just from what the assessor has written in the feedback it can giveà the learner self assessment and check their learning, so in future I will take more time on how I construct the test and how to mark it as this will give me a feedback on the progress of the SUT. 6. Reference List: * http://www.open.ac.uk/inclusiveteaching/pages/inclusive-teaching/barriers-to-learning.php Date accessed 8.11.12 * Tummons J ââ¬â (2009) Assessing learning in the lifelong learning sector. Exeter: Learning Matters * Gravells A (2012) Preparing to teach in the lifelong learning sector. London: Learning Matters * www.faculty.londondeanery.ac.uk
Saturday, November 9, 2019
Very Low to Moderate Income Housing Loans
Very Low to Moderate Income Housing Loans The following is a summary of information about low to moderate income housing loans available to individuals or families through the U.S. Department of Agricultures Rural Development program as listed in theà Catalog of Federal Domestic Assistanceà (CFDA). During the fiscal year 2015, aà total of $18.7 billion in loans were granted. The average direct loan granted was for $125,226 while the average guaranteed loan was for $136,360. Objectives To assist very low, low-income, and moderate-income households to obtain modest, decent, safe, and sanitary housing for use as a permanent residence in rural areas. Types of Assistance Direct Loans; Guaranteed/Insured Loans. Uses and Restrictions Direct and guaranteed loans may be used to buy, build, or improve the applicants permanent residence. New manufactured homes may be financed when they are on a permanent site, purchased from an approved dealer or contractor, and meet certain other requirements. Under very limited circumstances, homes may be re-financed with direct loans. Dwellings financed must be modest, decent, safe, and sanitary. The value of a home financed with a direct loan may not exceed the area limit. The property must be located in an eligible rural area. Assistance is available in the States, the Commonwealth of Puerto Rico, the U.S. Virgin Islands, Guam, American Samoa, the Commonwealth of Northern Marianas, and the Trust Territories of the Pacific Islands. Direct loans are made at the interest rate specified in RD Instruction 440.1, Exhibit B (available in any Rural Development local office), and are repaid over 33 years or 38 years for applicants whose adjusted annual income does not exceed 60 percent o f the area median income, if necessary to show repayment ability. Payment assistance is granted on direct loans to reduce the installment to an effective interest rate as low as one percent, depending on adjusted family income. Payment assistance is subject to recapture by the government when the customer no longer resides in the dwelling. There is no funding provided for deferred mortgage authority or loans for deferred mortgage assumptions. Guaranteed loans may be made to refinance either existing RHS Guaranteed Housing loans or RHS Section 502 Direct Housing loans. Guaranteed loans are amortized over 30 years. The interest rate is negotiated with the lender. Eligibility Requirements Applicants must have very low-, low- or moderate incomes. Very low-income is defined as below 50 percent of the area median income (AMI), low-income is between 50 and 80 percent of AMI; moderate income is below 115 percent of AMI. Families must be without adequate housing, but able to afford the housing payments, including principal, interest, taxes, and insurance (PITI). Qualifying repayment ratios are 29 percent for PITI to 41 percent for total debt. In addition, applicants must be unable to obtain credit elsewhere, yet have an acceptable credit history. Beneficiary Eligibility Applicants must meet eligibility requirements. Guaranteed Loan Low and Moderate income eligible. Credentials/Documentation Applicants may need to submit evidence of inability to obtain credit elsewhere, verification of income, debts, and other information on the application; plans, specifications, and cost estimates. This program is excluded from coverage under 2 CFR 200, Subpart E - Cost Principles. Application Procedures This program is excluded from coverage under 2 CFR 200, Uniform Administrative Requirements, Cost Principles, and Audit Requirements for Federal Awards. For direct loans, an application is made at the Rural Development field office serving the county where the dwelling is or will be located. For guaranteed loans, an application is made to a participating private lender. Award Procedure Rural Development field offices have authority to approve most Direct loan requests. Processing of guaranteed loans varies in each State. Consult your local telephone directory under U.S. Department of Agriculture for a Rural Development field office listing or visit the website http://offices.sc.egov.usda.gov/lcoator/app for a State Office listing. If no backlog exists, decisions on direct loan applications are made within 30 to 60 days. Requests for guarantee loans are acted upon in 3 days of receipt of the lenders request for guarantee. Range of Approval/Disapproval Time For direct loans, from 30 to 60 days subject to availability of funds, from the time the application is filed if no backlog of applications exists. A pre-qualification may be provided to potential direct loan applicants upon call or visit a Rural Development office, though results are not binding. For guarantees, a decision is required within 3 days of loan package submission by the approved lender. Information Contacts Regional or Local Office Consult your local telephone directory under United States Department of Agriculture for Rural Development field office number. If no listing, contact appropriate Rural Development State Office listed in Appendix IV of the Catalog or on the internet at rurdev.usda.gov/recd_map.html. Headquarters Office Director, Single Family Housing Direct Loan Division or Director Single Family Housing Guaranteed Loan Division, Rural Housing Service (RHS), Department of Agriculture, Washington, DC 20250. Telephone: (202) 720-1474 (direct loans), (202) 720-1452 (guaranteed loans).
Wednesday, November 6, 2019
Transforming Workforce In WWII essays
Transforming Workforce In WWII essays A Transforming Workforce During WWII: In the years preceding the Second World War, the United States, and the entire world, had experienced a crippling economic depression. There were large numbers of people out of work, and families struggling to make a better life. By the late 1930s the country just seemed to be getting back on its feet. Then, in 1941, America was drawn into the two-theater global war, and big changes were on their way. Immediately, droves of men from 17-40, prime working men, enlisted in the army and went overseas to fight. The military needed supplies; guns, ammo, uniforms, ships, planes, tanks, etc., and they turned to private industries, and the American people, to provide them with what was needed. Employers were in need of more workers, and so they hired non-traditional industrial workers such as women and African Americans. World War II thereby created an era of opportunity for American workers by creating a labor vacuum, increasing demand for produced goods, and encouraging women and Afr ican Americans to enter the workforce. As American men left their homes and families to join the Army, they also left their jobs vacant. The nation, obviously, did not cease to function when the war began, and these jobs still had to be done. Just one year after the attack on Pearl Harbor, the size of the armed forces more than doubled to around 5 million troops . These men who enlisted to fight were essentially the cream of the American industrial workforce. With 5 million job seeking Americans out of work prior to the start of the war, these job openings were eagerly filled. Although many industries which normally produced consumer goods switched to producing military supplies, work still needed to be performed. As our military entered WWII in two simultaneous theaters against very formidable enemies, they needed large quantities of suppl ...
Monday, November 4, 2019
Samples, Power Analysis, and Design Sensitivity Statistics Project
Samples, Power Analysis, and Design Sensitivity - Statistics Project Example A research that lacks either form of validity communicates possible deviations from actual properties of the research subjects and can therefore not be relied upon. Both external and internal validities are also susceptible to threats that must be monitored for a desired level of accuracy. The two forms of validities are therefore important in developing confidence in drawn conclusions and made inferences from a research initiative. They are however different in their specific scopes of applicability, and their threats. Internal validity for instance defines a research processââ¬â¢ independence from confounds that may influence observations contrary to the treatmentââ¬â¢s causal effects while external validity defines the degree of confidence in inferring research results to a population. Another difference between internal and external validity is their sets of threats. Threats to internal validity such as ââ¬Å"maturation,â⬠ââ¬Å"selection,â⬠ââ¬Å"instrumentati on,â⬠ââ¬Å"statistical regression,â⬠and ââ¬Å"attritionâ⬠induces bias on the causal effect relationship to impair accuracy of observation on treatment effect. Threats to external validity however include ââ¬Å"reactive effects of testing,â⬠ââ¬Å"interactive effect of selection,â⬠ââ¬Å"reactive effect of innovationâ⬠and ââ¬Å"multiple program interfaceâ⬠and induces barriers between properties of the used sample and other population segments (Fink, 2004, 78, 79). Research questions to which external validity is of primary concern are those questions that seek to establish relationships that are generally applicable to an entire population. Example is a research question to establish the relationship between gender and students performance in sciences that is psychologically hypothesized to be uniform across populations. Internal validity, however, is primary to research questions that seek to establish existence of a relationship between two
Saturday, November 2, 2019
Sound Field Amplification Systems in the Classroom Research Paper
Sound Field Amplification Systems in the Classroom - Research Paper Example Sound field amplification is beneficial toward every child that is placed in a National Diffusion Network (NDN) equipped-classrooms. (www.classroomhearing.org, 2011) An estimated 33 babies are born daily with significant hearing loss in the U.S. This puts them significantly behind in auditory learning skills. Children who have this setback need all the help they can get when they get into the classroom setting. Teachers that are using this FM microphone system have reported that it improves the amount of attention each student has, and also that they better understand the directions when they are given. This system also lowers the number of times the teachers need to repeat themselves which give them more time to move on and learn more material. Along with these benefits there are fewer discipline problems and students that have a better attitude toward learning. There are many distractions and interfering noise that come with teaching in a childââ¬â¢s classroom. This system helps to make them less noticeable. Students who had NDN equipped classrooms had better read and language scores after just one years. Fewer employees are needed to achieve the same or even a superior education, making the system more cost effectively. The classrooms that have NDN radios help make the children with disabilities seem more ââ¬Å"likeâ⬠everyone else, while they are achieving academic success at the same rate. These classroom amplification systems should not only be used in classrooms where there are hearing-impaired children present. Many children have perceptual difficulties while listening, without actually having any hearing loss. This would mean that a child hears perfectly well, but has difficulty grasping and interpreting the message that is being given. These types of children are present in every normal sized classroom. Sound field amplification cannot only help them to interpret the lessons better, but also help them realize that they do have what it takes t o be at the same level as their peers. This also helps with self confidence levels of children, making them all feels like they are equal in the class. Since most teachers are not taught how to tell whether or not a child is suffering from an auditory problem, they can sometimes mistake the children for having a disciplinary problem. Having these systems in every adolescent classroom would help to diminish the amount of disciplinary action that is taken upon children that have an underlying disability. Problem Statement Teachers and school often have a hard time projecting their voice so that all students can hear what is said at the front of the classroom, even in the back of the classroom. List of Definitions Sound Amplification System: a sound amplification system is a set of speakers inside the walls, or ceiling of a classroom and the teacher was a microphone around the teacherââ¬â¢s neck so that all students can hear even those in the back of the classroom. ANSI: American Na tional Standard Institute Microphone: a microphone is a device worn around the teacherââ¬â¢s neck that is connected with the speakers and the classroom, and works together
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